Compared to conventional reservoirs, pore structure and diagenetic alterations of unconventional tight sand oil reservoirs are highly heterogeneous. The Upper Triassic Yanchang Formation is a major tight-oil-bearing formation in the Ordos Basin, providing an opportunity to study the factors that control reservoir heterogeneity and the heterogeneity of oil accumulation in tight oil sandstones.The Chang 8 tight oil sandstone in the study area is comprised of fine-to medium-grained, moderately to well-sorted lithic arkose and feldspathic litharenite. The reservoir quality is extremely heterogeneous due to large heterogeneities in the depositional facies, pore structures and diagenetic alterations. Small throat size is believed to be responsible for the ultra-low permeability in tight oil reservoirs. Most reservoirs with good reservoir quality, larger pore-throat size, lower pore-throat radius ratio and well pore connectivity were deposited in high-energy environments, such as distributary channels and mouth bars. For a given depositional facies, reservoir quality varies with the bedding structures. Massive- or parallel-bedded sandstones are more favorable for the development of porosity and permeability sweet zones for oil charging and accumulation than cross-bedded sandstones.Authigenic chlorite rim cementation and dissolution of unstable detrital grains are two major diagenetic processes that preserve porosity and permeability sweet zones in oil-bearing intervals. Nevertheless, chlorite rims cannot effectively preserve porosity-permeability when the chlorite content is greater than a threshold value of 7%, and compaction played a minor role in porosity destruction in the situation. Intensive cementation of pore-lining chlorites significantly reduces reservoir permeability by obstructing the pore-throats and reducing their connectivity. Stratigraphically, sandstones within 1 m from adjacent sandstone-mudstone contacts are usually tightly cemented (carbonate cement > 10%) with low porosity and permeability (lower than 10% and 0.1 mD, respectively). The carbonate cement most likely originates from external sources, probably derived from the surrounding mudstone. Most late carbonate cements filled the previously dissolved intra-feldspar pores and the residual intergranular pores, and finally formed the tight reservoirs.The petrophysical properties significantly control the fluid flow capability and the oil charging/accumulation capability of the Chang 8 tight sandstones. Oil layers usually have oil saturation greater than 40%. A pore-throat radius of less than 0.4 μm is not effective for producible oil to flow, and the cut off of porosity and permeability for the net pay are 7% and 0.1 mD, respectively. 相似文献
Anaerobic degradation of mixtures of isomeric pristenes and phytenes by sedimentary bacterial communities was investigated. These isoprenoid alkenes were quickly metabolized without formation of the corresponding alkanes. Identification of several bacterial metabolites allowed us to confirm the key role played by hydration in the metabolism of alkenes. Despite the increasing production of 5α-stanols during incubation, attesting to the involvement of biohydrogenation, this process did not act significantly on the double bond of pristenes and phytenes. Their resistance is attributed to the lack of binding polar group(s) to anchor the substrate to the enzyme and thus allow the double bond to reach the reductive catalytic site. It therefore seems that microbial hydrogenation of pristenes and phytenes does not account for the presence of pristane and phytane in recent sediments during early diagenesis. 相似文献
A suite of reservoir cores (oil sands) from a single well in Bohai Bay Basin, East China, displayed a progressive increase in petroleum biodegradation extent on the basis of bulk composition and 25-norhopane content. This fits with the proposal that subsurface petroleum biodegradation is dominantly an anaerobic process and usually occurs at the oil–water contact. It is likely that sequential microbial degradation of hydrocarbons under anoxic conditions does not occur in a true stepwise fashion, but is controlled by various factors such as concentration and solubility of hydrocarbons and their diffusion rate to the oil/water contact. In fact, 25-norhopanes were formed prior to the complete elimination of the acyclic, and mono- and bicyclic alkanes. An inverse response of the 22S/(22S + 22R) ratio between each extended 17α(H)-hopane and its corresponding 25-norhopane was observed as severe biodegradation occurred, supporting the proposal that the 25-norhopanes originate from demethylation of hopanes. Field observation revealed that biomarkers without extended alkyl side chains, such as oleanane, gammacerane and β-carotane, have significant resistance to biodegradation and can be used as naturally occurring “internal standards” to evaluate variations in other biomarkers. The results suggest that the quantity of 25-norhopanes showed a minor increase as the hopanes decreased significantly, i.e. only partial hopane conversion to the corresponding 25-norhopanes. Alternative degradation pathways for hopanes might occur in reservoirs, in addition to C-25 demethylation. 相似文献
The Neoproterozoic Earth witnessed major global glaciation events with significant impact on paleoclimate and life evolution. The Tarim Craton in China preserves the records of four glaciation events during the Neoproterozoic which were correlated with the global glaciations, the nature and impact of these with respect to Neoproterozoic paleoclimatic–paleogeographic reconstructions remain unresolved. Here we report the discovery of a suite of source rocks from northeastern Tarim in which the strata formed during 655–635 Ma, corresponding to the interglacial period between the Sturtian and Marinoan diamictites. These source rocks are dominated by black shales and mudstones of up to 300 m thickness, and are characterized by high content of organic matter with TOC (total organic carbon) of 0.46%–3.5% (average 1.64%), vitrinite reflectance Ro of 1.28%–1.60%, and kerogen carbon isotope δ13C value between −28.58‰ and −31.89‰. Biomarker compounds indicate that the organic matter in these saprolite source rocks are made up of microorganisms such as algae and bacteria. The Pr and Ph values indicate a weak reducing–oxidizing environment, and most values of CIA (Chemical Index of Alteration) are >68, suggesting an interglacial temperate paleoclimate. The La/Th–Hf and Co/Th–La/Sc relationship suggests that the provenance of these rocks is mainly mixed felsic/mafic rocks. In the Tarim basin, these source rocks comprise an area of up to 90,000 km2 within Cryogenian rifts as inferred from seismic reflection profiles. Based on zircon UPb ages of volcanic rocks underlying the shale units, it is inferred the source rock formed during the temperate Sturtian glaciation events with subsequent extensive biotic recovery and high productivity. 相似文献
There has been a revival in hydrocarbon source rock characterization and development associated with growing interest in unconventional resources, where these fine-grained organic-rich rocks act as both source and reservoir. To-date, the exploration focus on shale reservoirs has been largely on marine systems. Lacustrine source rocks for conventional resources are geographically important, dominating regions such as China, Indonesia, and Brazil's resource-base. However, they have been generally untested for unconventional resources.There are a number of key differences in the nature of these hydrocarbon systems that should be considered when assessing whether lacustrine systems may represent future unconventional opportunities in areas where the conventional resource-base is dominated by lacustrine-sourced oil. Among the key differences between these depositional systems is the greater sensitivity to high frequency climatic variability within lacustrine systems. Lacustrine systems are highly sensitive to changes in the balance between precipitation and evaporation, which may lead to rapid changes in lake level, potentially exceeding 600 m. These changes in depositional conditions are geologically rapid and may occur over periods of thousands of years. Such changes can reduce the areal extent of potentially thick source rock intervals to only those portions of a basin where a permanent deep lake was present. Thus the core unconventional target area may be geographically limited compared with their marine counterpart. Although potentially areally limited, a review of many lacustrine source rocks suggests that their thicknesses are often significantly greater than marine source rocks. An examination of the more distal portions of lacustrine systems, where better source rock potential is present reveals that there is generally limited connectivity between source and conventional reservoir. In these settings, such as the Wind River basin (Waltman Shale), the hydrocarbons remain trapped within the shales, potentially leading to over-pressured hydrocarbon charged systems. Such conditions suggest that although areally limited, viable unconventional targets may exist, if suitable reservoir conditions are present. Finally, the character of the oils produced is different in these settings, with lacustrine oils being waxy and displaying different hydrocarbon generation and cracking kinetics. High wax oils display distinct flow characteristics, being more viscous, and may offer different production challenges than their non-waxy marine equivalents. Additionally, differences in their cracking kinetics may indicate that the timing of gas generation for shale gas plays may differ significantly from marine systems. 相似文献
Bad cement bond with water channeling or low strength cement is usually generated on the first and/or secondary interfaces which lie between the cement and casing, and the cement and formation, respectively. It is an inherently complicated problem to evaluate cement bond on the secondary interface (SICB) in a cased borehole. So we need to find a useful wave for evaluating SICB and provide its propagation features. To achieve this, we simulated the acoustic full waveform, 2-D spectrum and dispersion curves in cased boreholes based on the real axis integration method, and a propagator matrix. Simulation results indicated that “casing-cement mode” wave can be utilized to evaluate SICB, as it is most sensitive to water channeling on the secondary interface. Velocity of this mode wave is in between that of the casing wave and the formation wave, so that it is easy to extract it in time. The dispersion curves showed that the casing-cement wave is a dispersion wave, but not a pseudo-Rayleigh wave. Its velocity is obviously larger than vs of cement. Simulation results further indicated that the amplitude of casing-cement wave is decreasing with increasing cement sheath thickness, but not water channeling thickness, and its travel time is influenced by casing and cement together. Moreover, we investigated factors influencing the casing–cement wave and found that casing diameter and peak frequency are major factors influencing the amplitude and the travel time, while other factors, such as P-wave velocities of cement and wall thickness of casing, are minor factors. But none of these factors greatly influence bond index which is computed from the amplitude. So the bond index has an advantage over the amplitude during evaluating SICB. Formation wave is a helpful signal to evaluate low strength cement without water channeling, and its amplitude is mainly related to the velocities (or impedances) of both cement and formation except for formation attenuation and disturbance wave. Experimental data in calibration pits and field data detecting channeling demonstrated the simulation results. 相似文献
A large amount of deep oil has been discovered in the Tazhong Uplift, Tarim Basin whereas the oil source is still controversial. An integrated geochemical approach was utilized to unravel the characteristics, origin and alteration of the deep oils. This study showed that the Lower Cambrian oil from well ZS1C (1x) was featured by small or trace amounts of biomarkers, unusually high concentration of dibenzothiophenes (DBTs), high δ34S of DBTs and high δ13C value of n-alkanes. These suggest a close genetic relationship with the Cambrian source rocks and TSR alteration. On the contrary, the Middle Cambrian oils from well ZS1 (2a) were characterized by low δ13C of n-alkanes and relatively high δ34S of individual sulfur compounds and a general “V” shape of steranes, indicating a good genetic affinity with the Middle–Upper Ordovician source rocks. The middle Cambrian salt rock separating the oils was suggested to be one of the factors responsible for the differentiation. It was suggested that most of the deep oils in the Tazhong Uplift were mixed source based on biomarkers and carbon isotope, which contain TSR altered oil in varied degree. The percentage of the oils contributed by the Cambrian–Lower Ordovician was in the range of 19–100% (average 57%) controlled by several geological and geochemical events. Significant variations in the δ34S values for individual compounds in the oils were observed suggesting a combination of different extent of TSR and thermal maturation alterations. The unusually high DBTs concentrations in the Tazhong-4 oilfield suggested as a result of mixing with the ZS1C oil (1x) and Lower Ordovician oils based on δ34S values of DBT. This study will enhance our understanding of both deep and shallow oil sources in the Tazhong Uplift and clarify the formation mechanisms of the unusually high DBTs oils in the region. 相似文献
Phototrophic mats (microbial mats with a phototrophic top layer) are complex systems in terms of microbial diversity, biogeochemical cycles and organic matter (OM) turnover. It has been proposed that these mats were a predominant life form in Proterozoic shallow water settings, prior to the emergence of bioturbating organisms in the Ediacaran–Cambrian transition. For most of the Precambrian, microbial mats were not only quantitative important carbon fixing systems, but also influenced the transfer and transformation of OM before it entered the geosphere. The profound alteration of compound inventories during transit through microbial mats, implying substantial consequences for OM preservation in the Proterozoic, was recently proposed as a “mat-seal effect” [Pawlowska et al. (2012) Geology 41, 103–106]. To obtain a better understanding of the early diagenetic fate of primary produced OM in microbial mats, we studied a recent calcifying mat from a hypersaline lake in Kiritimati, which showed in the deeper mat layers a maximum 14Ccarbonate age of ∼1500 years. We particularly focused on OM entrapped in the carbonate matrix, because of the better potential of such biomineral-encapsulated OM to reach the geosphere before degradation (and remineralization). Our data indicate that selective preservation is important in phototrophic mats. While a diagenetic transformation of lipid fatty acids (FAs) was evident, their fatty acyl-derived hydrocarbon moieties were not introduced into protokerogen, which was instead mainly comprised of cyanobacterial and/or algal biomacromolecules. Our data support the proposed major impact of the “mat-seal effect” on OM turnover and preservation; i.e. the suppression of biosignatures derived from the upper mat layers, while signals of heterotrophic microbes thriving in deeper mat layers become preferentially preserved (e.g. high hopane/sterane ratios). This mechanism may have broad consequences for the interpretation of biomarkers from Proterozoic shelf environments, because biosignatures of phototrophic mat dwellers as well as planktonic signals may have become heavily biased by the production and turnover of OM in microbial mat systems. 相似文献
